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Homework answers / question archive / University of California, Los Angeles CHEMISTRY 171: PROBLEM SET 7 (11/13/15) 1)Determine the CFSE (crystal field stabilization energy) for each of the following: 6 Fe(CN)4- Ru(H O)3+ 6 Fe(H2O)3+ 6 PtCl2- 6 Co(NH3)3+ 4 CoCl2- (tetrahedral) 6 Cr(NH3)3+ Explain how ?o is affected by ?-acceptor ligands, ?-donor ligands and by ligands that don’t ?-bond Calculate the crystal field stabilization energy and predict whether the following exhibit a Jahn-Teller distortion: d2 octahedral and tetrahedral d3 octahedral and tetrahedral
University of California, Los Angeles
CHEMISTRY 171: PROBLEM SET 7 (11/13/15)
1)Determine the CFSE (crystal field stabilization energy) for each of the following:
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3 4 3 4
3 6 4 4
3 6 4
6 6
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6 6
6 6
6 6
a Explain these experimental observations using valence bond theory.
b. Explain these experimental observations using simple crystal field theory.
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