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coal gas can undergo a progress called methanation 3H2(g) + CO(g)=CH4(g) +H2O(g) delta H=? Determine the enthalpy change involved in the reaction of 300g of carbon monoxide in this methanation reaction, using the following reference equation and enthalpy change 1) 2H2(g) + O2(g)= 2H2O(g) delta H1= - 483
coal gas can undergo a progress called methanation
3H2(g) + CO(g)=CH4(g) +H2O(g) delta H=?
Determine the enthalpy change involved in the reaction of 300g of carbon monoxide in this methanation reaction, using the following reference equation and enthalpy change
1) 2H2(g) + O2(g)= 2H2O(g) delta H1= - 483.6KJ
2)2C(s) + O2(g) = 2CO(g) delta H2= - 221.0KJ
3) CH4(g) + 2O2(g)= CO2(g) + 2H2O(g) delta H3= - 802.7KJ
4)C(s) + O2(g) = CO2(g) delta H = - 393.5KJ
Expert Solution
ΔH = -2.20 x 103 kJ
Step-by-step explanation
HESS' LAW:
- The enthalpies of discrete chemical processes can be used to determine the enthalpy of an overall reaction
- Our goal to solve for the enthalpy change for the methanation reaction is to modify the chemical equations and combine them to arrive with: ?3H2?(g)+CO(g)→CH4?(g)+H2?O(g)?
- Take note, modifying the chemical equation changes the value of ΔH
SOLUTION:
Modifying the chemical equations, we get.
?3H2?(g)+23?O2?(g)→3H2?O(g)ΔH1?=−725.4 kJ?
- The equation was multiplied by ?23??
- The value of ΔH is multiplied by ?23??
?CO(g)→C(s)+21?O2(g) ΔH2?=+110.5 kJ?
- The equation was reversed and divided by 2
- The value of ΔH is multiplied by 2 and its sign is reversed
?CO2?(g)+2H2?O(g)→CH4?(g)+2O2?(g) ΔH3?=+802.7 kJ?
- The equation was reversed
- The sign of ΔH is reversed
?C(s)+O2?(g)→CO2?(g)ΔH4?=−393.5 kJ?
- No changes were made
Thus, we arrive with the overall ΔH value below
?ΔHoverall?=−725.4 kJ+110.5 kJ+802.7 kJ−393.5 kJ=−205.7 kJ?
FOR THE REACTION OF 300 g of CO:
The amount of heat involved in the reaction of CO is determined below:
?300 g CO×28 g1 mol CO?×1 mol CO−205.7 kJ?=−2.20×103 kJ??
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