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Ammonia is a nucleophile because it has a lone pair of electrons and a δ? charge on the N atom

Chemistry May 31, 2021

Ammonia is a nucleophile because it has a lone pair of electrons and a δ? charge on the N atom.

A nucleophile is a reactant that provides a pair of electrons to form a new covalent bond.

Sound familiar? This is the exact definition of a Lewis base. In other words, nucleophiles are Lewis bases.

A nucleophile is either a negative ion or a molecule with a δ? charge somewhere.

Ammonia doesn't carry a negative charge. But it has a lone pair of electrons. And nitrogen is more electronegative than hydrogen, so the nitrogen atom has a δ? charge.

So NH? can act as a nucleophile and attack the δ? C atom of an alkyl halide.

Here's a video on ammonia as a nucleophile.

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