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Homework answers / question archive / A set of three nucleophilic displacement reactions is shown below: CH3 CH2CI CI Cl CH3 H20, CH3CH20H SN1 reaction Which reaction (A, B, or C) proceeds the fastest? Which reaction (A, B, or C) proceeds the slowest? A set of three nucleophilic displacement reactions is shown below CH3 CH3 CH3Br CH3CHCH2CH2Br CH3CHCHBr 0% CH3 Nal acetone SN2 reaction Which reaction (A, B, or C) proceeds the fastest? Which reaction (A, B, or C) proceeds the slowest?

A set of three nucleophilic displacement reactions is shown below: CH3 CH2CI CI Cl CH3 H20, CH3CH20H SN1 reaction Which reaction (A, B, or C) proceeds the fastest? Which reaction (A, B, or C) proceeds the slowest? A set of three nucleophilic displacement reactions is shown below CH3 CH3 CH3Br CH3CHCH2CH2Br CH3CHCHBr 0% CH3 Nal acetone SN2 reaction Which reaction (A, B, or C) proceeds the fastest? Which reaction (A, B, or C) proceeds the slowest?

Chemistry

A set of three nucleophilic displacement reactions is shown below: CH3 CH2CI CI Cl CH3 H20, CH3CH20H SN1 reaction Which reaction (A, B, or C) proceeds the fastest? Which reaction (A, B, or C) proceeds the slowest?
A set of three nucleophilic displacement reactions is shown below CH3 CH3 CH3Br CH3CHCH2CH2Br CH3CHCHBr 0% CH3 Nal acetone SN2 reaction Which reaction (A, B, or C) proceeds the fastest? Which reaction (A, B, or C) proceeds the slowest?

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In SN1 reaction, rate of reaction depends upon stablity of carbocation. Stablity order is 3o>2o>1o

A forms 3o carbocation and hence will proceed fastest. B forms 1o carbocation and will proceed the slowest.

In SN2, the rate of reaction depends on stablity of transition state. For SN2 stablity order is 3o<2o<1o . Another factor is steric hinderance. For more rate less steric hinderence should be there.

A is 1o so it will proceed the fastest. B is also 1o but it has more steric hinderance compared to A. C is 2o so it will proceed with slowest rate.