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trying to fit kinetic model first order on QCM-D experiments data (frequency and time)

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trying to fit kinetic model first order on QCM-D experiments data (frequency and time). I flip the curve but am not sure about that then I stuck on predicting the desorption behaviour. I have formula but for the surface covrage not for frequency we will use almost the same formula but I don't know how. you have a look on excel file below.