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Homework answers / question archive / The concentration of elemental arsenic in 45 g of contaminated grain is to be determined using constant potential coulometry measured at a mercury cathode held at a potential of -0

The concentration of elemental arsenic in 45 g of contaminated grain is to be determined using constant potential coulometry measured at a mercury cathode held at a potential of -0

Chemistry

The concentration of elemental arsenic in 45 g of contaminated grain is to be determined using constant potential coulometry measured at a mercury cathode held at a potential of -0.350 V vs. SCE. The grain sample was extracted into 50.00 mL of acidic aqueous buffer and the resulting solution was characterized using the following coulometric reaction:

As (s) + 3 H+(aq) + 3e- -> AsH3(g)

The first column in the file is time (in seconds) and the second column is current (in amps). You may assume that 100% of the current acts to convert As(s) into AsH3(g). Determine the weight % of As in the original soil sample.

time (s) Current (A)
0 0.8235
25 0.621635
75 0.470581
125 0.357555
175 0.272987
225 0.209702
275 0.162348
325 0.126916
375 0.100406
425 0.080566
475 0.065722
525 0.054615
575 0.046304
625 0.040085
675 0.035434
725 0.031947
775 0.029346
825 0.027397
875 0.025936
925 0.024843
975 0.024029
1025 0.023418
1075 0.02296
1125 0.022616
1175 0.02236

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