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Acid Ka CB Kb     H2CO3 4

Chemistry Jan 25, 2021
Acid Ka CB Kb    
H2CO3 4.2 x 10-7 HCO3- 2.4 x 10-8    
HCO3- 4.8 x 10-11 CO32- 2.1 x 10-4    



You are to prepare a "carbonate" buffer with pH of 10.35. Youare given carbonic acid (H2CO3). sodiumhydrogen carbonate (NaHCO3), and sodium carbonate(Na2CO3).

H2CO3 + H2O <----> H3O+ +HCO3-

HCO3- + H2O <---> H3o+ +CO3-

CO32- + H2O <--->HCO3- + OH-

a) Using the information in the chart about Ka/Kb values, whichspecies will you use? Explain your choice?
b) Which component will be present in the larger amount?
c) You are given a 0.025M solution of the acid and a 0.025Msolution of the conjugate base. Calculate how many mL of each youwould use to make the buffer.
 

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