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Homework answers / question archive / Delgado Community College CHEM 222 Chapter 8

Delgado Community College CHEM 222 Chapter 8

Chemistry

Delgado Community College

CHEM 222

Chapter 8.Alkenes and Alkynes II

Multiple Choice Section: 8.6

1)The Oxymercuration-Demercuration reaction produces a                                    addition.

 

    1. Markovnikov

 

    1. Anti-Markovnikov

 

    1. Syn addition

 

    1. Anti addition

 

    1. A and D

 

    1. B and C

 

 

Section: 8.7

  1. The Hydroboration-Oxidation reaction produces a                             addition.

 

    1. Markovnikov

 

    1. Anti-Markovnikov

 

    1. Syn addition

 

    1. Anti addition

 

    1. A and D

 

    1. B and C

 

Section: 8.12

  1. The addition of Br2 in CCl4 to an alkene produces a                                addition.

 

    1. Markovnikov

 

    1. Anti-Markovnikov

 

    1. Syn addition

 

    1. Anti addition

 

    1. A and D

 

    1. B and C

 

 

Section 8.12

  1. What is the product of the following reaction?

 

 

 
 
 

 

 

 

    1. I

 

    1. II

 

    1. III

 

    1. IV

 

 

Section: 8.13

  1.          reactions form products where the reagent adds to a specific location over another. reactions form products where the reagent adds to form a specific stereochemical form.

 

    1. Stereoselective, Stereospecific

 

    1. Regiospecific, Stereospecific

 

    1. Stereospecific, Regiospecific

 

    1. Stereospecific, Stereoselective

 

 

Section: 8.2, 8.5, 8.14

  1. Which of the following reagents produces Markovnikov additions?

 

    1. HBr/CCl4 added to double bond

 

    1. H2O/HA added to a double bond

 

    1. Br2/H2O

 

    1. A and B

 

    1. B and C

 

    1. A and C

 

    1. all of the them

 

    1. none of them

 

 

Section: 8.14

  1. What is the product of the following reaction?

 

 

 

 

 

    1. I

 

    1. II

 

    1. III

 

    1. IV

 

 

Section: 8.15

  1. What is the product of the following reaction?

 

 

 

 

 

    1. I

 

    1. II

 

    1. III

 

    1. IV

 

 

Section: 8.17

  1. What is the product of the following reaction?

 

 

 

 

 

    1. I

 

    1. II

 

    1. III

 

    1. IV

 

 

Section: 8.2, 8.17

  1. What is the correct order of reagents needed for the following reaction?

 

 

 
 
 

 

 

 

    1. 1) HBr/CCl4 2) Sodium Methoxide/Methanol 3) KMnO4, OH–, H2O, heat

 

    1. 1) HBr/CCl4 2) Sodium Methoxide/Methanol 3) O3, CH2Cl2, –78°C 4) Zn/AcOH

 

    1. 1) HBr/H2O2 2) Sodium Methoxide/Methanol 3) O3,CH2Cl2, –78°C 4) Zn/AcOH

 

    1. 1) HBr/H2O2 2) Potassium tert-butoxide 3) KMnO4, OH–, H2O, heat

 

    1. 1) HBr/H2O22) Potassium tert-butoxide 3) O3, CH2Cl2, –78°C 4) Zn/AcOH

 

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