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Half-reactions: Au3+(aq) + 3e- Au(s) Cd2+(aq) + 2e-→ Cd(s) E: +1
Half-reactions: Au3+(aq) + 3e- Au(s) Cd2+(aq) + 2e-→ Cd(s) E: +1.50 V E?=-040 V electrolytic voltaic is being oxidized. 6 is being reduced. Cd2 (aq) is acting as an reducing agent. Cd(s) Au(s) is acting as an oxidizing agent. 4 moles of electrons are transferred. Au (aq) The reaction is a(n) cell.
Expert Solution
Au3+ changed in to Au .The oxidation state of Au decreased from
3+ to 0 . Hence it Au3+ is reduced **
Cd changed to Cd2+ . its oxidation state increased from
zero to 2+ . Since there is an increase in oxidation state.
Cd i s undergone oxidation **
The species which undergone oxidation is reducing agent. Hence
Cd is reducing agent**
The species which undergone reduction is oxidizing agent. Hence
Au3+ is oxidizing agent **
electrons gained must be = electron lost in the overall reaction
Hence a total of 6 electrons involved. **
The species with higher reduction potential will have a strong tendency
to get reduced. This happens spontaneously. A voltaic cell
involve spontaneous reaction. here Au3+ has higher reduction
potential value ,but it undergone reduction .Hence the cell is
voltaic cell **
using these points we can answer
1)
Cd(s) is being oxidized
2)
Au3+(aq) is being reduced
3)
Cd(s) is acting as a reducing agent
4)
Au3+ is acting as a oxidizing agent
5) 6 mols of electrons are transferred
6)The reaction is a voltaic cell
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