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The concentration of elemental arsenic in 45 g of contaminated grain is to be determined using constant potential coulometry measured at a mercury cathode held at a potential of -0
The concentration of elemental arsenic in 45 g of contaminated grain is to be determined using constant potential coulometry measured at a mercury cathode held at a potential of -0.350 V vs. SCE. The grain sample was extracted into 50.00 mL of acidic aqueous buffer and the resulting solution was characterized using the following coulometric reaction:
As (s) + 3 H+(aq) + 3e- -> AsH3(g)
The first column in the file is time (in seconds) and the second column is current (in amps). You may assume that 100% of the current acts to convert As(s) into AsH3(g). Determine the weight % of As in the original soil sample.
| time (s) | Current (A) |
| 0 | 0.8235 |
| 25 | 0.621635 |
| 75 | 0.470581 |
| 125 | 0.357555 |
| 175 | 0.272987 |
| 225 | 0.209702 |
| 275 | 0.162348 |
| 325 | 0.126916 |
| 375 | 0.100406 |
| 425 | 0.080566 |
| 475 | 0.065722 |
| 525 | 0.054615 |
| 575 | 0.046304 |
| 625 | 0.040085 |
| 675 | 0.035434 |
| 725 | 0.031947 |
| 775 | 0.029346 |
| 825 | 0.027397 |
| 875 | 0.025936 |
| 925 | 0.024843 |
| 975 | 0.024029 |
| 1025 | 0.023418 |
| 1075 | 0.02296 |
| 1125 | 0.022616 |
| 1175 | 0.02236 |
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