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Allyl chloride is to be produced in a 12-fit long 2 in ID tube operating as an isothermal PFR

Chemistry Jan 30, 2023

Allyl chloride is to be produced in a 12-fit long 2 in ID tube operating as an isothermal PFR. The feed is a 4:1 molar ratio of propylene to chlorine and it enters at a feed rate of 0.85 1bmole/hr and at 2 atm of pressure. The reactor pressure may be assumed constant. The reaction network is given by: Cl2 + C3H6-C3H5Cl + HCI Cl2 + C3H6-C3H 6Cl2 The rate constants have units of lbmoles/(hr-ft3-atm?) and are given by 27200 k1 = 206000exp RT 6860 k2 = 11.7exp RT where T is in degrees Rankine and R is in Btu/(1bmole-R). The rate expressions are r1 = KIP C3HePCIz 12 = k2P C3H6PCIz Compute the molar flow rates of Cl2, C3HsCl and C3HoCl2 at 550, 600 and 650 F. Plot these flow rates versus reactor length. Notice that the temperature increase changes the relative production rates of C3HsCl and C3HC12 and therefore their relative yields. Comment on why this is the case.

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